A phenomenological approach is proposed to derive plasmon energies for C materials as a function of mass density q and sp2 fraction f. It is shown that the energy of the graphite in-plane (p and p + r) and out-of-plane plasmons, as well as the energy of the diamond bulk (r) plasmon are correctly reproduced by the model. Crucial factors in this respect – and responsible for the deviation from a free electron picture – are the energy of interband transitions associated with plasmon excitation and the screening of p electrons due to r electron polarization. Plasmon energies, derived as a function of q and f, are discussed.
Plasmon features in electron energy loss spectra from carbon materials
Calliari, Lucia;Filippi, Massimiliano
2007-01-01
Abstract
A phenomenological approach is proposed to derive plasmon energies for C materials as a function of mass density q and sp2 fraction f. It is shown that the energy of the graphite in-plane (p and p + r) and out-of-plane plasmons, as well as the energy of the diamond bulk (r) plasmon are correctly reproduced by the model. Crucial factors in this respect – and responsible for the deviation from a free electron picture – are the energy of interband transitions associated with plasmon excitation and the screening of p electrons due to r electron polarization. Plasmon energies, derived as a function of q and f, are discussed.File in questo prodotto:
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